New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}
Identifieur interne : 000157 ( France/Analysis ); précédent : 000156; suivant : 000158New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}
Auteurs : Samia Benmansour [France, Espagne] ; Fatima Setifi [France, Algérie] ; Smail Triki [France] ; Jean-Yves Salaün [France] ; Fanny Vandevelde [France] ; Jean Sala-Pala [France] ; Carlos J. G Mez-García [Espagne] ; Thierry Roisnel [France]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2007-01.
English descriptors
- KwdEn :
Abstract
New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Url:
DOI: 10.1002/ejic.200600449
Affiliations:
- Algérie, Espagne, France
- Communauté valencienne, Région Bretagne
- Brest, Rennes
- Université de Bretagne Occidentale
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Chem.</title><idno type="ISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2007-01">2007-01</date><biblScope unit="volume">2007</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="186">186</biblScope><biblScope unit="page" to="194">194</biblScope></imprint><idno type="ISSN">1434-1948</idno></series><idno type="istex">D0F151EAB21E95BC0184CBD6AF2319FB8DB10DD4</idno><idno type="DOI">10.1002/ejic.200600449</idno><idno type="ArticleID">EJIC200600449</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1434-1948</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bridging ligands</term><term>Coordination polymers</term><term>Cyano carbanions</term><term>Magnetic properties</term><term>Multidimensional networks</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</div></front></TEI><affiliations><list><country><li>Algérie</li><li>Espagne</li><li>France</li></country><region><li>Communauté valencienne</li><li>Région Bretagne</li></region><settlement><li>Brest</li><li>Rennes</li></settlement><orgName><li>Université de Bretagne Occidentale</li></orgName></list><tree><country name="France"><region name="Région Bretagne"><name sortKey="Benmansour, Samia" sort="Benmansour, Samia" uniqKey="Benmansour S" first="Samia" last="Benmansour">Samia Benmansour</name></region><name sortKey="Roisnel, Thierry" sort="Roisnel, Thierry" uniqKey="Roisnel T" first="Thierry" last="Roisnel">Thierry Roisnel</name><name sortKey="Sala Ala, Jean" sort="Sala Ala, Jean" uniqKey="Sala Ala J" first="Jean" last="Sala-Pala">Jean Sala-Pala</name><name sortKey="Salaun, Jean Ves" sort="Salaun, Jean Ves" uniqKey="Salaun J" first="Jean-Yves" last="Salaün">Jean-Yves Salaün</name><name sortKey="Setifi, Fatima" sort="Setifi, Fatima" uniqKey="Setifi F" first="Fatima" last="Setifi">Fatima Setifi</name><name sortKey="Triki, Smail" sort="Triki, Smail" uniqKey="Triki S" first="Smail" last="Triki">Smail Triki</name><name sortKey="Triki, Smail" sort="Triki, Smail" uniqKey="Triki S" first="Smail" last="Triki">Smail Triki</name><name sortKey="Vandevelde, Fanny" sort="Vandevelde, Fanny" uniqKey="Vandevelde F" first="Fanny" last="Vandevelde">Fanny Vandevelde</name></country><country name="Espagne"><region name="Communauté valencienne"><name sortKey="Benmansour, Samia" sort="Benmansour, Samia" uniqKey="Benmansour S" first="Samia" last="Benmansour">Samia Benmansour</name></region><name sortKey="G Mez Arcia, Carlos J" sort="G Mez Arcia, Carlos J" uniqKey="G Mez Arcia C" first="Carlos J." last="G Mez-García">Carlos J. G Mez-García</name></country><country name="Algérie"><noRegion><name sortKey="Setifi, Fatima" sort="Setifi, Fatima" uniqKey="Setifi F" first="Fatima" last="Setifi">Fatima Setifi</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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